{"id":224,"date":"2020-04-23T15:36:05","date_gmt":"2020-04-23T13:36:05","guid":{"rendered":"http:\/\/perso.ens-lyon.fr\/denis.frath\/?p=224"},"modified":"2020-04-23T17:07:44","modified_gmt":"2020-04-23T15:07:44","slug":"highly-efficient-photoswitch-in-diarylethene-based-molecular-junctions","status":"publish","type":"post","link":"https:\/\/perso.ens-lyon.fr\/denis.frath\/2020\/04\/23\/highly-efficient-photoswitch-in-diarylethene-based-molecular-junctions\/","title":{"rendered":"Highly Efficient Photoswitch in Diarylethene-Based Molecular Junctions"},"content":{"rendered":"<p>Our article is available to read at <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c01213\" target=\"_blank\" rel=\"noopener\">J. Am. Chem. Soc.<\/a><\/p>\n<p><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c01213\" target=\"_blank\" rel=\"noopener\"><img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-221 alignleft\" src=\"http:\/\/perso.ens-lyon.fr\/denis.frath\/wp-content\/uploads\/2020\/04\/ja0c01213_0005-300x145.gif\" alt=\"\" width=\"300\" height=\"145\" \/><\/a>Thin layers of diarylethene oligomers (oligo(DAE)) were deposited by electrochemical reduction of a diazonium salt on glassy carbon and gold electrodes. The layers were fully characterized using electrochemistry, XPS, and AFM, and switching between open and closed forms using light was evidenced. Solid-state molecular junctions (MJs), in which a C-AFM tip is used as the top contact, were fabricated with total layer thicknesses fixed at 2\u20133 nm and 8\u20139 nm, i.e. below and above the direct tunneling limit. DAE was then photoswitched between its open and closed forms. Oligo(DAE) MJs using the open form of DAE are highly resistive while those with DAE in the closed form are more conductive. ON\/OFF ratios of 2\u20133 and 200\u2013400 were obtained for 3-nm- and 9-nm-thick DAE MJs, respectively.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Our article is available to read at J. Am. Chem. Soc. Thin layers of diarylethene oligomers (oligo(DAE)) were deposited by electrochemical reduction of a diazonium salt on glassy carbon and gold electrodes. The layers were fully characterized using electrochemistry, XPS, and AFM, and switching between open and closed forms using light was evidenced. Solid-state molecular [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-224","post","type-post","status-publish","format-standard","hentry","category-article"],"_links":{"self":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts\/224","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/comments?post=224"}],"version-history":[{"count":6,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts\/224\/revisions"}],"predecessor-version":[{"id":268,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts\/224\/revisions\/268"}],"wp:attachment":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/media?parent=224"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/categories?post=224"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/tags?post=224"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}