{"id":602,"date":"2025-06-24T09:39:31","date_gmt":"2025-06-24T07:39:31","guid":{"rendered":"https:\/\/perso.ens-lyon.fr\/denis.frath\/?p=602"},"modified":"2025-06-24T09:43:10","modified_gmt":"2025-06-24T07:43:10","slug":"602","status":"publish","type":"post","link":"https:\/\/perso.ens-lyon.fr\/denis.frath\/2025\/06\/24\/602\/","title":{"rendered":"\u03c0-Expansion as gateway to viologen-based pimers"},"content":{"rendered":"<p>Our article is available to read at <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2025\/sc\/d5sc01361e\" target=\"_blank\" rel=\"noopener\">Chem. Sci.<\/a><\/p>\n<p><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2025\/sc\/d5sc01361e\" target=\"_blank\" rel=\"noopener\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter\" src=\"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D5SC01361E&amp;imageInfo.ImageIdentifier.Year=2025\" alt=\"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D5SC01361E&amp;imageInfo.ImageIdentifier.Year=2025\" width=\"399\" height=\"192\" \/><\/a>The present article reports on a new and efficient synthetic strategy towards tetracene-bipyridiniums. On the basis of extensive experimental analyses supported by DFT simulations, we report the first observation of a mixed valence complex formed in solution under standard conditions from an unconstrained bis-viologene derivative.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Our article is available to read at Chem. Sci. The present article reports on a new and efficient synthetic strategy towards tetracene-bipyridiniums. On the basis of extensive experimental analyses supported by DFT simulations, we report the first observation of a mixed valence complex formed in solution under standard conditions from an unconstrained bis-viologene derivative.<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-602","post","type-post","status-publish","format-standard","hentry","category-article"],"_links":{"self":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts\/602","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/comments?post=602"}],"version-history":[{"count":7,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts\/602\/revisions"}],"predecessor-version":[{"id":614,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/posts\/602\/revisions\/614"}],"wp:attachment":[{"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/media?parent=602"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/categories?post=602"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/perso.ens-lyon.fr\/denis.frath\/wp-json\/wp\/v2\/tags?post=602"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}